| Authors: | M. Shanthi, Pavithra; J. Hanumantha, Prashanth; Albuquerque, Taciana; Gattu, Bharat; Kumta, Prashant N. |
| Title: | Novel Composite Polymer Electrolytes of PVdF-HFP Derived by Electrospinning with Enhanced Li-Ion Conductivities for Rechargeable LithiumSulfur Batteries |
| Type: | Journal Article |
| Publisher: | ACS Applied Energy Materials
|
| Year: | 2018 |
| Volume: | 1 |
| Issue: | 2 |
| Start Page: | 483-494 |
| End Page: | |
| DOI: | 10.1021/acsaem.7b00094 |
| WEB-link: | https://doi.org/10.1021/acsaem.7b00094 |
| Abstract: | Composites of poly(vinylidene fluoride-co-hexafluoro propylene) (PVdF-HFP) incorporating 10 wt % bis(trifluoromethane)sulfonimide lithium salt (LiTFSI) and 10 wt % particles of nanoparticulate silica (nm-SiO2), nanoparticulate titania (nm-TiO2), and fumed silica (f-SiO2) were prepared by electrospinning. These membranes served as host matrix for the preparation of composite polymer electrolytes (CPEs) following activation with lithium sulfur battery electrolyte comprising 50/50 (vol %) dioxolane/dimethoxyethane with 1 M LiTFSI and 0.1 M LiNO3. The membranes consist of layers of fibers with average fiber diameter of 0.1-0.2 ým. CPEs with f-SiO2 exhibited higher ionic conductivity with a maximum of 1.3 ý 10-3 S cm-1 at 25 ýC obtained with 10 wt % filler compositions. The optimum CPE based on PVdF-HFP with 10 wt % f-SiO2 exhibited enhanced charge-discharge performance in Li-S cells at room-temperature eliminating polysulfide migration, delivering initial specific capacity of 895 mAh g-1 at 0.1 C-rate and a very low electrolyte/sulfur (E/S) ratios between 3:1 to 4:1 mL.g-1. The CPEs also exhibited very stable cycling behavior well over 100 cycles (fade rate < 0.056%/cycle), demonstrating their suitability for Li-S battery applications. In addition, the interconnected morphological features of PVdF-HFP result in superior mechanical properties (200-350% higher tensile strength). Higher Li-ion conductivity, higher liquid electrolyte uptake (>250%) with dimensional stability, lower interfacial resistance, and higher electrochemical stability are some of the attractive attributes witnessed with these CPEs. With these improved performance characteristics, the PVdF-HFP system is projected herein as suitable polymer electrolytes system for high-performance Li-S rechargeable batteries.
|
| File: | (10846K) |
